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In Vegas? No, but there's a quarry full of deathclaws if you feel like a challenge.

There are no Behemoths in New Vegas, but I'm sure there are legendary monsters who are strong as those.

I haven't played New Vegas yet, but from what I have read about it, no there isn't. The Super Mutants from New Vegas are Mariposa Muties, only Vault 87 Muties turn into Behemoths.

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